Article

Arhive, 2001, № 2

Thermophysical Properties of Materials

2001. V. 39. № 2. P. 233–243

Khasanshin I.V., Kudin L.S., Pogrebnoi A.M., Motalov V.B.

Thulium trichloride: Thermochemistry of molecular and ionic associates

The composition of saturated vapor over thulium trichloride is studied using the method of high-temperature mass spectrometry. Neutral $(\mathrm{TmCl}_3)_n$ and charged $\mathrm{Cl}$-$(\mathrm{TmCl}_3)_n$ associates up to $n=5$ and $8$, respectively, have been registered for the first time in the temperature range from $868$ to $1110$ K. Partial pressures p(atm) of the vapor components are determined. The second and third laws of thermodynamics are used to calculate the sublimation enthalpies $\Delta_s H^\circ$ ($298$ K) in the form of monomeric and associated molecules, as well as the enthalpies of formation $\Delta_f H^\circ$ ($298$ K) of gaseous molecules and ions.

Article reference:
Khasanshin I.V., Kudin L.S., Pogrebnoi A.M., Motalov V.B. Thulium trichloride: Thermochemistry of molecular and ionic associates, High Temp., 2001. V. 39. № 2. P. 233