Article

Thermophysical Properties of Materials
2009. V. 47. № 3. P. 342–351
Galashev A.E., Rakhmanova O.R., Tchukanov V.N.
The absorption of carbon and nitrogen monoxides by ultradisperse aqueous system: Computer experiment
Annotation
The method of molecular dynamics is used to investigate the effect of absorption of carbon and nitrogen monoxides on the spectral characteristics of a disperse aqueous system. The absorption of $\text{CO}$ molecules causes the reduction of the real and imaginary parts of permittivity, and the absorption of $\text{NO}$ molecules results in smoothing out of the frequency dependence of these characteristics, which corresponds to that of a system of clusters of pure water. The integral absorptance and reflectance of IR radiation decrease after the attachment of $\text{CO}$ molecules to water clusters and undergo insignificant changes as a result of absorption of $\text{NO}$ molecules. An increase is observed in the integral power of emission of infrared radiation by disperse aqueous systems which absorbed $\text{CO}$ or $\text{NO}$ molecules. The clustering of water vapor causes an abrupt reduction of the number of scattering centers and the anti-greenhouse effect.
Article reference:
Galashev A.E., Rakhmanova O.R., Tchukanov V.N. The absorption of carbon and nitrogen monoxides by ultradisperse aqueous system: Computer experiment, High Temp., 2009. V. 47. № 3. P. 342