Article

Short Communications
2017. V. 55. № 4. P. 611–614
Martynov G.A.
Phase transitions and fluctuations in classical statistical mechanics
Annotation
It is shown that allowance for fluctuations leads to the appearance of additional terms in the Hamiltonian of the system and in the thermodynamic parameters of the substance. As a result, it becomes possible to describe the critical phenomena and phase transitions of liquid–vapor within classical statistical mechanics (without taking into account fluctuations, this is impossible).
Article reference:
Martynov G.A. Phase transitions and fluctuations in classical statistical mechanics, High Temp., 2017. V. 55. № 4. P. 611