Article

Arhive, 2000, № 1

Thermophysical Properties of Materials

2000. V. 38. № 1. P. 33–36

Ibragimova L.B., Smekhov G.D., Shatalov O.P., Eremin A.V., Shumova V.V.

Dissociation of $\mathrm{CO}_2$ molecules in a wide temperature range

Expressions are derived for the dissociation rate constants of molecules of carbon dioxide in the temperature range from $300$ to $40000$ K under both thermally equilibrium and nonequilibrium conditions. Under nonequilibrium conditions, the rate constants are represented as a two-temperature dependence (on the gas temperature $T$ and on the unified temperature $T_V$ of all vibrational modes of $\mathrm{CO}_2$) and as a one-temperature dependence in which averaged vibrational nonequilibrium is included.

Article reference:
Ibragimova L.B., Smekhov G.D., Shatalov O.P., Eremin A.V., Shumova V.V. Dissociation of $\mathrm{CO}_2$ molecules in a wide temperature range, High Temp., 2000. V. 38. № 1. P. 33