Article

Thermophysical Properties of Materials
2014. V. 52. № 6. P. 830–839
Faizullin M.Z., Vinogradov A.V., Koverda V.P.
Properties of gas hydrates formed by nonequilibrium condensation of molecular beams
Annotation
Low-temperature crystallization of amorphous materials has been analyzed theoretically taking into account nonstationary nucleation. The kinetics of crystallization of amorphous water layers, formed by depositing molecular beams on a substrate cooled by liquid nitrogen, has been investigated by differential thermal analysis. The conditions of gas hydrate formation in low-temperature amorphousice layers saturated with carbon dioxide have been studied. The glass-transition and crystallization temperatures of the gas hydrates have been determined from the change in dielectric properties upon heating. Under the deep-metastability conditions, crystallization of water–gas layers leads to the formation of crystallohydrates. Gas molecules are captured by the avalanche-like nucleation of crystallization centers and, therefore, are not displaced by the moving crystal–melt interface. Gas-hydrate samples formed in nonequilibrium water–gas layers are convenient for studying their thermophysical properties.
Article reference:
Faizullin M.Z., Vinogradov A.V., Koverda V.P. Properties of gas hydrates formed by nonequilibrium condensation of molecular beams, High Temp., 2014. V. 52. № 6. P. 830